Reduction of Cobalt (III)-Poly (4-vinylpyridine) Complexes by Ferrous Sulfate
نویسندگان
چکیده
منابع مشابه
Polyoxometalate-modulated self-assembly of polystyrene-block-poly(4-vinylpyridine).
Polyoxometalates can serve as active components to induce and modulate the micellization behavior of polystyrene-block-poly(4-vinylpyridine).
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In the centrosymmetric polymeric title compound, {[CoGd(2)(C(14)H(8)N(2)O(5))(4)(H(2)O)(4)]·4H(2)O}(n), the Gd(III) cation is coordinated by one water mol-ecule and four pyridine-4-carboxamido-isophthalate (L) anions in a distorted square-anti-prismatic arrangement, while the Co(II) cation, located on an inversion center, is coordinated by two pyridyl-N atoms, two carboxyl-ate-O atoms and two w...
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Aerobic reactions of Co(O(2)CMe)(2).4H(2)O with di-2-pyridyl ketone oxime (Hpko) in the presence of counterions (ClO(4)(-), PF(6-)) give the tetranuclear, mixed-valence cobalt(II/III) clusters [Co(II)(2)Co(III)(2)(OR)(2)(O(2)CMe)(2)(pko)(4)S(2)]X(2) [R = H, S = MeOH, X = ClO(4) (1); R = Me, S = EtOH, X = PF(6) (2)] depending on the solvent mixture. Complexes 1 and 2 are the first Co members in ...
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In the centrosymmetric polymeric title compound, {[CoHo(2)(C(14)H(8)N(2)O(5))(4)(H(2)O)(4)]·4H(2)O}(n), the Ho(III) ion is coordinated by one water mol-ecule and four 5-(pyridine-4-carboxamido)-isophthalate (L) ligands in a distorted square-anti-prismatic arrangement. The Co(II) ion, located on an inversion center, is coordinated by two pyridine N atoms, two carboxyl-ate O atoms and two water m...
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ژورنال
عنوان ژورنال: NIPPON KAGAKU KAISHI
سال: 1972
ISSN: 2185-0925,0369-4577
DOI: 10.1246/nikkashi.1972.2420